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Synthesis and reactions of and catalytic homogeneous hydrogenation by chlorocarbonyl(o-(diphenylphosphino)-N,N-dimethylaniline)iridium(I) and chlorocarbonyl(o-(diphenylphosphino)-N,N-dimethylbenzylamine)iridium(I)

✍ Scribed by Rauchfuss, Thomas B.; Clements, James L.; Agnew, Stephen F.; Roundhill, D. Max.

Book ID: 120661050
Publisher: American Chemical Society
Year: 1977
Tongue: English
Weight: 562 KB
Volume: 16
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic50170a010

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Recently we showed by a single crystal structure determination that the complex chlorocarbonyl-((odiphenylphosphino)-N,Ndimethylaniline)iridium-(I), IrCl(CO)PN has a planar geometry and a stereochemistry with mutually trans dimethylamino and carbonyl ligands [I]. Furthermore, from spectroscopic comp

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The crystal structure of 5,6-benzo-4-diphenylphosphino-2-phenyl-l,3,2-dioxaborinane I indicates the occurrence of an interaction between the r-systems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group of the diphenylphosphino group. Complexes of compound 1 with PtCl,, PdCl,, and Cul w