Synthetic, structural, stereochemical, and catalytic studies on carbonyliridium(I) complexes of o-(diphenylphosphino)-N,N-dimethylaniline, o-(diphenylphosphino)-N,N-dimethylbenzylamine, 2-(diphenylphosphino)-N,N-dimethylethylamine, and 3-(diphenylphosphino)-N,N-dimethylpropylamine
β Scribed by Roundhill, D. Max; Bechtold, Rebecca A.; Roundhill, Stephanie G. N.
- Book ID
- 127332345
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 815 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Recently we showed by a single crystal structure determination that the complex chlorocarbonyl-((odiphenylphosphino)-N,Ndimethylaniline)iridium-(I), IrCl(CO)PN has a planar geometry and a stereochemistry with mutually trans dimethylamino and carbonyl ligands [I]. Furthermore, from spectroscopic comp
A series of rhenium(I) tricarbonyl complexes with bidentate P,O donor ligand o-(diphenylphosphino)benzaldehyde (Pβ©O) and its Schiff base P,N donor ligand o-[diphenylphosphino)benzylidene]analine (Pβ©N) have been synthesized and structurally characterized. All the complexes of the type [ReX(CO)(3)(LL)