Structure and reactions of benzo-4-diphenylphosphino-2-phenyl-1,3,2-dioxaborinane

✍ Scribed by G. N. Nikonov; A. S. Balueva; A. A. Karasik; I. A. Litvinov; S. R. Prokhorova; O. N. Kataeva

• Book ID: 102846584
• Publisher: John Wiley and Sons
• Year: 1994
• Tongue: English
• Weight: 528 KB
• Volume: 5
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.520050109

✦ Synopsis

The crystal structure of 5,6-benzo-4-diphenylphosphino-2-phenyl-l,3,2-dioxaborinane I indicates the occurrence of an interaction between the r-systems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group of the diphenylphosphino group. Complexes of compound 1 with PtCl,, PdCl,, and Cul were synthesized, Compound 1 and its complexes are readily hydrolyzed in solution to give diphenylphosphine and its corresponding complexes (NMR).