## Abstract The reduction of the phosphacobaltocenium salt [CoCp\*(2,5‐PC~4~__t__Bu~2~H~2~)]^+^[BPh~4~]^−^ (3; Cp\*=pentamethylcyclopentadienyl) by magnesium in tetrahydrofuran (THF) furnishes the stable air‐sensitive phosphacobaltocene [CoCp\*(2,5‐PC~4~__t__Bu~2~H~2~)] (4) in yields of up to 80 %.
✦ LIBER ✦
Synthesis and Properties of [NiCp*(2,5-tBu2PC4H2)], a 20-Valence-Electron Phosphanickelocene
✍ Scribed by Claire Burney; Duncan Carmichael; Kareen Forissier; Jennifer C. Green; François Mathey; Louis Ricard
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 251 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0947-6539
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We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educación y Ciencia for a postdoctoral fellowship.