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Synthesis and Properties of [NiCp*(2,5-tBu2PC4H2)], a 20-Valence-Electron Phosphanickelocene

✍ Scribed by Claire Burney; Duncan Carmichael; Kareen Forissier; Jennifer C. Green; François Mathey; Louis Ricard


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
251 KB
Volume
11
Category
Article
ISSN
0947-6539

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Synthesis and Properties of [CoCp*(2,5-P
✍ Claire Burney; Duncan Carmichael; Kareen Forissier; Jennifer C. Green; François 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract The reduction of the phosphacobaltocenium salt [CoCp\*(2,5‐PC~4~__t__Bu~2~H~2~)]^+^[BPh~4~]^−^ (3; Cp\*=pentamethylcyclopentadienyl) by magnesium in tetrahydrofuran (THF) furnishes the stable air‐sensitive phosphacobaltocene [CoCp\*(2,5‐PC~4~__t__Bu~2~H~2~)] (4) in yields of up to 80 %.

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We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educación y Ciencia for a postdoctoral fellowship.