Formation and Structure of a Sterically Protected Molybdenum Hydride Complex with a 15-Electron Configuration: [(1,2,4-C5H2tBu3)Mo(PMe3)2H]+
โ Scribed by Miguel Baya; Jennifer Houghton; Jean-Claude Daran; Rinaldo Poli
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 133 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
โฆ Synopsis
We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educaciรณn y Ciencia for a postdoctoral fellowship.
๐ SIMILAR VOLUMES
The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th
The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ฯญ