Synthesis and Properties of Metal Complexes of Ether-bonded Porphyrin–Chlorin Dimer
✍ Scribed by Ekaterina G. Levinson; Andrei F. Mironov
- Book ID
- 111729592
- Publisher
- Royal Society of Chemistry
- Year
- 1994
- Tongue
- English
- Weight
- 117 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0959-9436
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The synthesis of 4-amino-1,2,4-triazole linked porphyrin-chlorin dimer and porphyrin dimer is described. New cationic porphyrin dimers were synthesized via the alkylation of the nitrogen atoms of 4,4%-bipyridine and 1,2-di-(4-pyridyl)ethene by meso-monobromomethylporphyrin. These cationic bisporphyr
A chlorin-bacteriochlorin dimer containing a Zn II -complex of a chlorin e 6 derivative covalently bound with the cycloimide of bacteriochlorin p via a spacer group was obtained.
## f&M. Dihematoporphyrin ether (DHE) has been synthesised by two separate procedures; these routes also allow the synthesis of ether linked porphyrin dimers containing one or two vinyl groups rather than hydroxyethyl side chains. The latter dimers, but not DHE, have anti-cancer activity. Hematop