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Synthesis and Properties of Membranes of Poly(diphenylacetylenes) Having Fluorines and Hydroxyl Groups

✍ Scribed by Shida, Yuichi; Sakaguchi, Toshikazu; Shiotsuki, Masashi; Sanda, Fumio; Freeman, Benny D.; Masuda, Toshio

Book ID: 126440555
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 90 KB
Volume: 39
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma052082n

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## SYNOPSIS l-Phenyl-2-[rn-(trimethylgermyl)phenyl]acetylene (m-Me,GeDPA) and 1-phenyl-2-[p-(trimethylgermyl)phenyl]acetylene @-Me,GeDPA) polymerized with TaC1,-cocatalyst systems t o provide in high yields new polymers having weight-average molecular weights over 1 X lo6. Poly(m-Me3GeDPA) was a y