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Synthesis and gas permeation properties of poly(diphenylacetylenes) having bulky alkyl/silyl and hydroxy groups

โœ Scribed by Yanming Hu; Toshikazu Sakaguchi; Masashi Shiotsuki; Fumio Sanda; Toshio Masuda

Book ID
108208016
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
298 KB
Volume
282
Category
Article
ISSN
0376-7388

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Polymerization of diphenylacetylenes hav
Polymerization of diphenylacetylenes having very bulky silyl groups and polymer properties
โœ Masahiro Teraguchi; Toshio Masuda ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 133 KB ๐Ÿ‘ 1 views

Polymerization and polymer properties of 1-phenyl-2-[4-(triphenylsilyl)phenyl]acetylene (pPh 3 SiDPA) and 1-phenyl-2-[4-(triisopropylsilyl)phenyl]acetylene (piPr 3 SiDPA), which have very bulky silyl groups, were examined. These monomers polymerized in good yields in the presence of TaCl 5 -based ca