Novel diphenylacetylenes with both trimethylsilyl groups and other substituents (R 2 C 6 H 3 C CC 6 H 4 -p-SiMe 3 , R = m,Cl, m,Cl, m,Br, m,Br, m,Me, m,Me, respectively) were polymerized with TaCl 5 -n-Bu 4 Sn to produce solvent-soluble polymers (2a-f). Most polymers (2a-e) had high molecular weight
โฆ LIBER โฆ
Synthesis and Properties of F-Containing Poly(diphenylacetylene) Membranes
โ Scribed by Sakaguchi, Toshikazu; Shiotsuki, Masashi; Sanda, Fumio; Freeman, Benny D.; Masuda, Toshio
- Book ID
- 111675263
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 96 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## SYNOPSIS l-Phenyl-2-[rn-(trimethylgermyl)phenyl]acetylene (m-Me,GeDPA) and 1-phenyl-2-[p-(trimethylgermyl)phenyl]acetylene @-Me,GeDPA) polymerized with TaC1,-cocatalyst systems t o provide in high yields new polymers having weight-average molecular weights over 1 X lo6. Poly(m-Me3GeDPA) was a y
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