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Synthesis and Physicochemical Study of Binuclear Copper(II) Chelates Containing an Asymmetric Exchanged Fragment

โœ Scribed by V. V. Lukov; V. A. Kogan; V. M. Novotortsev; Yu. P. Tupolova; I. E. Gevorkyan


Book ID
106522092
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
71 KB
Volume
31
Category
Article
ISSN
1070-3284

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Ligand exchange reactions between copper
โœ J. Stach; R. Kirmse; W. Dietzsch; G. Lassmann; V.K. Belyaeva; I.N. Marov ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 417 KB

enolates) were found to have an equilibrium constant ofK=4. The kinetics of ligand exchange reactions studied by means of stopped-flow ESR measurements are reported. The concentration-time curves recorded for all reactions investigated correspond to simple second-order rate laws. The rate constants