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Synthesis and characterization of an unexpected asymmetric binuclear copper(I) complex containing 4-vinyl-pyridine

โœ Scribed by Kai Jiang; Dong Zhao; Li-Bing Guo; Chuan-Jian Zhang; Rui-Na Yang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
592 KB
Volume
22
Category
Article
ISSN
0256-7660

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Synthesis and Reductive Complexation Pro
โœ Jean-Bernard Regnouf De Vains; Roger Lamartine; Bernard Fenet; Claude Bavoux; Al ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 758 KB

The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati