Binuclear Copper(II) Complexes of Bis(1,4,7-triazacyclononane) Ligands Containing Tri- and Tetramethylene Bridging Groups. An Equilibrium and Structural Study
โ Scribed by Zhang, Xiaoping; Hsieh, Wen-Yuan; Margulis, T. N.; Zompa, Leverett J.
- Book ID
- 127256898
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 768 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Two new binucleating ligands, 1,3โbis[(4,7โdimethylโ1,4,7โtriazacyclononanโ1โyl)methyl]benzene (L^memx^) and 1,2โbis[(4,7โdimethylโ1,4,7โtriazacyclononanโ1โyl)methyl]benzene(L^meox^), have been prepared from 1,4,7โtriazatricyclo[5.2.1.0^4,10^]decane and applied in the synthesis of the c
Synthesis, crystal structure and magnetic properties of the binuclear copper ( 11) complex of a new bis ( 1 , 4 7 10-tetraazacyclododecane) ligand help to elucidate the factors that determine the electronic and magnetic pruperties in the polynuclear bio-site. The ligands that comprise two macmycles