𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 2

✍ Scribed by Helmut Spreitzer; Andrea Pichler; Wolfgang Holzer; Manocher Shahabi

Book ID
102861477
Publisher
John Wiley and Sons
Year
1997
Tongue
German
Weight
517 KB
Volume
80
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Khusimone (1), one of the main odor‐donating compounds of vetiver oil, is subject of the following study on structure/odor relationship. Ring opening of the carbonyl‐functionalized bridge of the tricyclic khusimone leads to the bicyclic structures 2a/b. The enantioselective approach to these degraded structures is described, and the olfactory consequences are studied. Starting point of the synthesis is an enantiomerically pure enone ester which is easily obtainable from camphorsulfonic acid.

πŸ“œ SIMILAR VOLUMES

Synthesis and Odor of Chiral Partial Str
Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 1
✍ Helmut Sprdizer; Andrea Pichler; Wolfgang Holzer; Irene Toth; Bettina Zuchart πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 German βš– 496 KB πŸ‘ 1 views

Dedicated with best personal wishes to Prof. Dr. W. Fleischhucker on the occasion of his 65th birthday (16.1X.96) Khusimone (l), one of the main odor-donating compounds of vetiver oil is subject of the following study on structure/odor relationship. The omittance of the ethano bridge of the tricycli

ChemInform Abstract: Synthesis and Odor
ChemInform Abstract: Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 3.
✍ H. SPREITZER; A. PICHLER; W. HOLZER; C. SCHLAGER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 1 views

Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 3. -Khusimone (I) is one of the main odor-donating compounds of vetiver oil. For structure-odor relationship studies the bicyclic partial structure (II) missing the methano bridge is considered. Unexpectedly, (II) cannot be obtained

Synthesis and odor of chiral partial str
Synthesis and odor of chiral partial structures of Ξ²-vetivone, Part 2
✍ Helmut Spreitzer; Iris Piringer; Andrea Pichler; Wolfgang Holzer; Jana Ruzicka; πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 132 KB πŸ‘ 1 views

Several stereoisomeric, monocyclic analogs of (-)-␀-vetivone (1), one of the main constituents of vetiver oil, were studied to examine if the olfactory properties of (-)-␀-vetivone (1) could be reproduced from these structurally simpler, synthetically accessible compounds. The effects of diastereome