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Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 1

โœ Scribed by Helmut Sprdizer; Andrea Pichler; Wolfgang Holzer; Irene Toth; Bettina Zuchart

Publisher
John Wiley and Sons
Year
1997
Tongue
German
Weight
496 KB
Volume
80
Category
Article
ISSN
0018-019X

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โœฆ Synopsis

Dedicated with best personal wishes to Prof. Dr. W. Fleischhucker on the occasion of his 65th birthday (16.1X.96) Khusimone (l), one of the main odor-donating compounds of vetiver oil is subject of the following study on structure/odor relationship. The omittance of the ethano bridge of the tricyclic khusimone leads to a bicyclic system. The stereoselective approach to this degraded structure is described, and the olfactory properties are studied. The key step of the synthesis of the hydrindane nucleus is based on a highly diastereoselective conjugate addition to a chiral 0x0-cyclopentene-2-carboxylate.

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Part of the Ph.D. thesis [l].

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