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Synthesis and multinuclear magnetic resonance investigation of some 1,3-selenazole and 1,3-selenazoline derivatives

✍ Scribed by Helmut Duddeck; Ralf Bradenahl; Lech Stefaniak; Jaroslaw Jazwinski; Bohdan Kamienski

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
117 KB
Volume
39
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^1^H, ^13^C, ^15^N and ^77^Se NMR data of various annelated 1,3‐selenazoles and ‐1,3‐selenazolines are discussed in terms of tautomerism, configurational and conformational preference as well as HOMO–LUMO transition energies. The interpretations are corroborated by semi‐empirical calculations. Divergencies in solution‐ and solid‐state ^77^Se NMR data are discussed. Copyright © 2001 John Wiley & Sons, Ltd.

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