## Abstract ^1^H, ^13^C, ^14^N and ^15^N NMR data are reported for a series of mesoinoic 1,3,4‐triazoles and some of their salts. The results obtained show that the molecules studied exist in the cyclic mesoionic form with delocalization of the positive charge over the ring atoms. The corresponding
Multinuclear magnetic resonance study of some mesoionic 1,3-diphenyltetrazoles with various exocyclic groups
✍ Scribed by Wojciech Bocian; Jaroslaw Jaźwiński; Wiktor Koźmiński; Lech Stefaniak; Graham A. Webb
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 294 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^1^H, ^13^C, ^14^N and ^15^N NMR methods were applied to the study of some Type A mesoionic 1,3‐diphenyltetrazoles with various exocyclic groups. The ring structures of these tetrazoles are confirmed by the nitrogen NMR data. The shielding of N‐4 increases consecutively by amounts of ca 10 ppm as the bonded exocyclic atom changes from S to C to O.
📜 SIMILAR VOLUMES
## Abstract Mesoionic compounds 1–8 were synthesized and their ^1^H, ^13^C, ^14^N, ^15^N and ^17^O NMR spectra recorded in the absence and presence of the chiral dirhodium complex Rh^\*^. It is shown that the enantiomers of the mesoionic compounds could be differentiated satisfactorily (‘dirhodium