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Synthesis and Functionalization of 4-Halomethyl-1,3-selenazoles.

✍ Scribed by Karlheinz Geisler; Wolf-Diethard Pfeiffer; Cornelia Mueller; Elvira Nobst; Ehrenfried Bulka; Peter Langer

Publisher: John Wiley and Sons
Year: 2003
Weight: 114 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200341178

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## Abstract The reaction of __N__,__N′__‐diarylselenoureas **16** with phenacyl bromide in EtOH under reflux, followed by treatment with NH~3~, gave __N__,3‐diaryl‐4‐phenyl‐1,3‐selenazol‐2(3__H__)‐imines **13** in high yields (__Scheme 2__). A reaction mechanism __via__ formation of the correspondi