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Synthesis and Molecular Structure of Binuclear Tin (IV) Complex Bridged by Terephthalate Anion

✍ Scribed by Han-Dong Yin; Chuan-Hua Wang; Chun-Lin Ma; Yong Wang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
222 KB
Volume
20
Category
Article
ISSN
0256-7660

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✦ Synopsis


Synthesis and Molecular

Structure of Binuclear Tin( IV) Complex Bridged by Terephthalate Anion YIN, Han-Doq'(FXO WANG, Ch~an-H~a(Zf$q) MA, C h ~n -L h ( ~& # ) WANG, Yong(3B) Depcutmeru of Chemistry, Liaocheng Teachers University, LMocheng 252059, China ?hetitk m l e x [ @ & h ( a @ H > ( k @ t h 8 h k ) ( c & o H ) S m ] .2CH30H was synthesized by the reaction d Ph&Cl tion and dranrteri2gd by elemental analysis, IR and 'H NMR spectra, and the crystal stnscbve wss determined by X-ray sinwith space group P2,/n, a = 1.5199(5) mn, b = 0.9ooO(3) nm, c=1.=(6) ~1 , ~=113.970(5)", 232, V=2.2755 (U) nm', D,= 1.413 glad, p = 1.146 mm-', F(000) = 980, R = 0.0353, WR = 0.0606. In the crystals d EMlplex. theiinatomrrenderedfive-coordinateinadistortedtirgonal bipyramidalshueture. with teRphthalate in the mdar ratio d2:l in methanol sdu-gleaptal~mstudy.Theerystalbelonggtomoaoeliaie I ~~T K & sis. molecular structure binuclear, triphenyltin( IV) , terephthalate, synthe-


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