## Abstract The title complex [(H~2~O)~2~(IMI)~3~Ni(TCB)Ni(IMI)~3~β(H~2~O)~2~] H~2~O (TCB = 1,2,4,5βbenzenetetracarboxylato teβtravalent anion; IMI = imidazole) has been prepared by the reaction of Ni(IMI)~3~(Ac)~2~ and TCB in aqueous solution. The crystal structure has been determined by singleβcr
Synthesis and Molecular Structure of Binuclear Tin (IV) Complex Bridged by Terephthalate Anion
β Scribed by Han-Dong Yin; Chuan-Hua Wang; Chun-Lin Ma; Yong Wang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 222 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0256-7660
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β¦ Synopsis
Synthesis and Molecular
Structure of Binuclear Tin( IV) Complex Bridged by Terephthalate Anion YIN, Han-Doq'(FXO WANG, Ch~an-H~a(Zf$q) MA, C h ~n -L h ( ~& # ) WANG, Yong(3B) Depcutmeru of Chemistry, Liaocheng Teachers University, LMocheng 252059, China ?hetitk m l e x [ @ & h ( a @ H > ( k @ t h 8 h k ) ( c & o H ) S m ] .2CH30H was synthesized by the reaction d Ph&Cl tion and dranrteri2gd by elemental analysis, IR and 'H NMR spectra, and the crystal stnscbve wss determined by X-ray sinwith space group P2,/n, a = 1.5199(5) mn, b = 0.9ooO(3) nm, c=1.=(6) ~1 , ~=113.970(5)", 232, V=2.2755 (U) nm', D,= 1.413 glad, p = 1.146 mm-', F(000) = 980, R = 0.0353, WR = 0.0606. In the crystals d EMlplex. theiinatomrrenderedfive-coordinateinadistortedtirgonal bipyramidalshueture. with teRphthalate in the mdar ratio d2:l in methanol sdu-gleaptal~mstudy.Theerystalbelonggtomoaoeliaie I ~~T K & sis. molecular structure binuclear, triphenyltin( IV) , terephthalate, synthe-
π SIMILAR VOLUMES
A b s t r a c t Six new p-phthalato binuclear oxovanadium(1V) complexes, namely [(VO)z(PHTH)-(L)2]SO, (L denotes '2,2'-bipyridine (bpy); 1,lO-phenanthroline (phen); 4,4'-dimethyl-2,2'-bipyridine (Mezbpy); 5-nitrcz1 ,lO-phenanthroline (NOZ-phen); 5-chIo~1,lO-phenanthroline (C1-phen) and 5methyl-1,lO-