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Mechanochemical Control of Synthesis and Structures of Aqua-Bridged Binuclear Nickel(II) Benzoate Complexes

✍ Scribed by Anirban Karmakar; Rupam J. Sarma; Jubaraj B. Baruah

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
359 KB
Volume
2006
Category
Article
ISSN
1434-1948

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## Abstract Two novel binuclear nickel(II) and cobalt(III) complexes with two or three dissimilar bridges, [Ni~2~(tacn)~2~(__ΞΌ__‐N~3~)~2~(__ΞΌ__‐O~2~CPh)](ClO~4~)β‹…H~2~O (1) and [Co~2~(tacn)~2~(__ΞΌ__‐N~3~)(__ΞΌ__‐OH)(__ΞΌ__‐O~2~CPh)](ClO~4~)~3~ (2) (tacn=1,4,7‐triazacyclononane), were synthesized and s