Three binuclear copper(I1) complexes, [Cu2@ -L)@ -N3)](C104)2. 1.5 EtOH (l), [Cu2@ -L)@ -MeO)(C10,)]-C10,. EtOH (2) and [Cu2@ -L)@ -C3H3N2)](C10,)2 .2 H,O, (3) where L is the pentadentale bridging ligand derived from 5-(tert-butyl)-2-hydroxybenzene-1,3-dicarbaldehyde his(benzoy1hydrazone) (HL) were
Synthesis, structure and characterization of binuclear copper(II) complexes
β Scribed by Rui-Na Yang; Baeyu Xue; Dong-Mei Wang; Dou-Man Jin; Jun Chen; Ming-Xing Li
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 450 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0256-7660
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The crystal structure of the binuclear Cu(II) complex [Cu(flu) 2 DMF] 2 (flu = deprotonated N-3-trifluromethylphenylanthranilic acid: DMF = dimethylformamide) has been solved by single crystal X-ray diffractometry. It crystallizes in the monoclinic space group P2 1 /c with Z = 2. The in-frared and e
## Abstract A new binucleating bis(terdentate) ligand, 3,5β[3βbis(2βpyridyl)pyrazoleβ1βylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (ΞΌβpyrazolato)(ΞΌβhydroxido)βbridged binuclear and tetranuclear complexes [L^2^Cu~2~(ΞΌβOH)(ClO~