Synthesis and magnetic properties of copper(II)bis(phenylsulphinyl)ethane complexes

✍ Scribed by Ze-Chang Huang; Ruo-Hua Zhang; Jia-Chen Yang; Dai-Zheng Liao

• Publisher: Springer
• Year: 1995
• Tongue: English
• Weight: 167 KB
• Volume: 20
• Category: Article
• ISSN: 0340-4285
• DOI: 10.1007/bf00136419

✦ Synopsis

Two Cu u complexes, [Cu2(c~-L)C14]'H20 (I) and Cu2(R-L)C14 (2) I-~-L and R-L=meso-and rac-PhS(O)(CHz)zS(O)Ph, respectively], were synthesized and characterized by elemental analysis, i.r. spectra and molar conductances. In each case, the Cu u ion bonds to the S:O moiety through oxygen, and may be bridged by the ligand (~-L or R-L). From magnetic moment measurements at room temperature and variable temperature magnetic susceptibilities, we suggest that complexes (1) and (2) exhibit weak ferromagnetic behaviour.