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Synthesis, Structure and Magnetic Properties of Two New Homotrinuclear Bis(oxamato) Copper (II) Complexes

✍ Scribed by Qing-Lun Wang; Dai-Zheng Liao; Sm-Ping Yan; Zong-Hui Jiang; Peng Cheng

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 447 KB
Volume: 20
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.20020201117

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~