Synthesis and Investigations on Nitrido(phthalocyaninato)rhenium Complexes
β Scribed by Karsten Frick; Ulrich Ziener; Michael Hanack
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 266 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-1948
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π SIMILAR VOLUMES
The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound
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The synthesis of highly soluble chloro(phthalocyaninato)indi-cyaninato)indium(III) (4f) was prepared by the reaction of (n-C 5 H 11 ) 8 PcInCl (4a) with PhLi. The high solubility of the um(III) complexes R x PcInCl (3a: R 1 = tert-butyl, R 2 = H, x = 4 and 4a: R 1 = R 2 = n-pentyl, x = 8), and their