Novel Nitrido- and Oxo(phthalocyaninato) Complexes of Molybdenum, Tungsten and Rhenium

✍ Scribed by Karsten Frick; Sanjiv Verma; Jörg Sundermeyer; Michael Hanack

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 341 KB
• Volume: 2000
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(200005)2000:5<1025::aid-ejic1025>3.0.co;2-s

✦ Synopsis

The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound