Nitrosyl and Oxo Complexes of Molybdenum
β Scribed by J. A. McCleverty; M. D. Ward
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 7 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The reaction between [Mo(CO)~4~(NO)(ClAlCl~3~)] and the sterically hindered diphosphanes (Pβ©P) 1,3βbis(diisopropylphosphanyl)propane (dippp, a), 1,2βbis(diisopropylphosphanyl)ethane (dippe, b), 1,1β²βbis(diisopropylphosphanyl)ferrocene (dippf, c) and 1,2βbis(dicyclohexylphosphanyl)ethane
The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of (tBu 4 Pc)WN ( 6) with PPh 3 leading, after several steps, to the diamagnetic compound