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Monomer−Dimer Equilibria of Oxo/Imido Complexes of Heptavalent Rhenium: Theoretical and Spectroscopic Investigations

✍ Scribed by Philip Gisdakis; Notker Rösch; Éva Bencze; Janos Mink; Isabel S. Gonçalves; Fritz E. Kühn

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
537 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The tetra(4-t-butyl)phthalocyanine derivative of the m-oxo dimer of Fe was studied by ESR and Mo ¨ssbauer spectroscopic and magnetic susceptibility methods. The Mo ¨ssbauer spectrum of the iron complex shows DE Q = 1.34 mm s À1 and = 0.14 mm s À1 . The susceptibility data measured as a function of t