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Synthesis and Emission Properties of 1,6-Methano[10]annulene-3,4-dicarboximides

✍ Scribed by Kuroda, Shigeyasu; Oda, Mitsunori; Tamura, Naoko; Miyatake, Ryuta; Matsumoto, Naoko; Horino, Yoshikazu; Miyawaki, Daisuke


Book ID
118272869
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
885 KB
Volume
83
Category
Article
ISSN
0385-5414

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πŸ“œ SIMILAR VOLUMES


Generation and [4+2] cycloaddition of 1,
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A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.

Reaktionen des 4-Bromo-1,6-methano[10]an
✍ Richard Neidlein; GΓΌnter SchrΓΆder πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 German βš– 537 KB

4 R = Me (69%) NH,NH'Bu K,CO,, DMF 2 (61%) ' B k . 2 IB U 5 (54%) 6 (4%) 7 ( 5 % ) aa ab 9 Mit Hydrazinen reagiert 1 zu Pyrazolen: NH,NH, und NH,NHMe lassen sich mit 1 leicht und schnell zu den Verbindungen 3 und 4 umsetzen (Schema 2), wlhrend NH,NH(t-Bu) bei 25" in 56% Ausbeute uberraschend das u