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A Short-Step Synthesis of 1,6-Methano[10]annulene-3,4-dicarboximides and Their Benzene-, Naphthalene-, and Thiophene-Annulated Compounds

✍ Scribed by Oda, Mitsunori; Nakamura, Tomomi; Neha, Miyako; Miyawaki, Daisuke; Ohta, Akira; Kuroda, Shigeyasu; Miyatake, Ryuta


Book ID
126317835
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
368 KB
Volume
2014
Category
Article
ISSN
1434-193X

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Generation and [4+2] cycloaddition of 1,
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A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.