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Synthesis and electrochemistry of new tetrathiafulvalene (TTF) dendrimers:X-ray crystal structure of a tetrafunctionalised TTF core unit

✍ Scribed by Wang, Changsheng; Bryce, Martin R.; Batsanov, Andrei S.; Goldenberg, Leonid M.; Howard, Judith A. K.


Book ID
111644085
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
573 KB
Volume
7
Category
Article
ISSN
0959-9428

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Tetrathiafulvalene (TTF) fused to acenap
✍ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 210 KB

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el