✦ LIBER ✦

Tetrathiafulvalene (TTF) fused to acenaphthyleno[1,2b][1,4]dithiine: synthesis and X-ray crystal structure of a new π-electron donor system

✍ Scribed by Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 210 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02417-4

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution electrochemistry and X-ray crystal structure of which are reported.

📜 SIMILAR VOLUMES

ChemInform Abstract: 4,4′,5,5′-Tetrakis(

ChemInform Abstract: 4,4′,5,5′-Tetrakis(2-thienyl)tetrathiafulvalene (TT-TTF): Synthesis and First X-Ray Crystal Structure of a Thiophene-Substituted TTF Electron Donor.

✍ A. CHARLTON; A. E. UNDERHILL; G. WILLIAMS; M. KALAJI; P. J. MURPHY; D. E. HIBBS; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views