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Preparation, solid-state characterisation and X-ray crystal structure of a 1:1 complex of tetrathiafulvalene and m-dinitrobenzene (TTF-mDNB)

✍ Scribed by Bryce, Martin R.; Davies, Stephen R.; Hursthouse, Michael B.; Motevalli, Majid


Book ID
121241691
Publisher
Royal Society of Chemistry
Year
1988
Tongue
English
Weight
430 KB
Volume
9
Category
Article
ISSN
1472-779X

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Tetrathiafulvalene (TTF) fused to acenap
✍ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 210 KB

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el