Synthesis and DNA binding of bisintercalating complexes of the type [(dpq)2Ru(phen-n-SOS-n-phen)Ru(dpq)2]4+
✍ Scribed by Craig R. Brodie; Janice R. Aldrich-Wright; Edith Glazer; Nathan Luedtke; Yitzhak Tor
- Book ID
- 108403846
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 104 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0162-0134
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## Abstract Polypyridyl ligand 9a,13a‐dihydro‐4,5,9,14‐tetraaza‐benzo[b]triphenylene‐11‐yl)‐phenyl‐methanone (BDPPZ) and its complexes [Ru(bpy)~2~BDPPZ]^2+^, [Ru(dmb)~2~BDPPZ]^2+^ and [Ru(phen)~2~BDPPZ]^2+^ (where bpy = 2,2′‐bipyridine, dmb = 4,4′‐dimethyl‐2,2′‐bipyridine, phen = 1,10‐phenanthrolin
## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13(10__H__,12__H__)‐dione, phen=1,10‐phenanthroline) were synthesized and characterized by ES‐MS, ^1^H‐NMR spectroscopy, and elemental analysis. The int
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