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Experimental and theoretical studies on the DNA-binding and spectral properties of water-soluble complex [Ru(MeIm)4(dpq)]2+

✍ Scribed by Lan-Mei Chen; Jie Liu; Jin-Can Chen; Shuo Shi; Cai-Ping Tan; Kang-Cheng Zheng; Liang-Nian Ji

Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
466 KB
Volume
881
Category
Article
ISSN
0022-2860

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## Abstract The ligand pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13‐diamine (ppn) and its Ru^II^ complexes [Ru(bpy)~2~(ppn)]^2+^ (**1**; bpy=2,2′‐bipyridine) and [Ru(phen)~2~(ppn)]^2+^ (**2**; phen=1,10‐phenanthroline) were synthesized and characterized by elemental analysis, electrospray MS, ^1

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Experimental and Density-Functional-Theory (DFT) Studies on the DNA-Binding Trend and Spectral Properties of the Ruthenium Complexes [Ru(4,7-dmp)(bdip)]2+ and [Ru(bpy)2(bdip)]2+ (4,7-dmp=4,7-Dimethyl-1,10-phenanthroline, bdip=2-(1,3-Benzodioxol-4-yl)-1H-imidazo[4,5-f] [1,10]phenanthroline, bpy=2,2′-bipyridine)
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## Abstract The new ligand bdip (=2‐(1,3‐benzodioxol‐4‐yl)‐1__H__‐imidazo[4,5‐__f__][1,10]phenanthroline) and its Ru^II^ complexes [Ru(4,7‐dmp)~2~(bdip)]^2+^ (**1**; 4,7‐dmp=4,7‐dimethyl‐1,10‐phenanthroline) and [Ru(bpy)~2~(bdip)]^2+^ (**2**; bpy=2,2′‐bipyridine) were synthesized and characterized