A series of \(\mathrm{Bi}_{3}^{+}{ }^{3} R E_{5} \mathrm{O}_{12}\)-type phases ( \(R E=\mathrm{Y}, \mathrm{La}, \mathrm{Pr}, \mathrm{Nd}, \mathrm{Sm}\), \(\mathrm{Eu}, \mathrm{Gd}, \mathrm{Tb}, \mathrm{Dy}, \mathrm{Ho}, \mathrm{Er}, \mathrm{Yb}, \mathrm{Lu})\) has been prepared in air at \(950^{\cir
✦ LIBER ✦
Synthesis and Crystallochemical Characterization of the Tb1−xBixSrO3-Type Solid Solution
✍ Scribed by R. Horyń; Z. Bukowski; M. Wołcyrz
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 224 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0022-4596
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We report on the synthesis and crystal structure of TlPbCl 3 which can only be prepared by a high pressure synthesis. In similar experiments solid solutions of the type Tl 1؊x Rb x PbCl 3 (0(x(0.25) and TlPbCl 3؊x Br x (0(x(2.5) were prepared. The structural parameters are given. All compounds are i