Synthesis and crystal structures of zirconium(IV) nitrate complexes (NO2)[Zr(NO3)3(H2O)3]2(NO3)3, Cs[Zr(NO3)5], and (NH4)[Zr(NO3)5](HNO3)
β Scribed by I. V. Morozov; A. A. Fedorova; D. V. Palamarchuk; S. I. Troyanov
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 371 KB
- Volume
- 54
- Category
- Article
- ISSN
- 1573-9171
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## Abstract The oxidation of copper, zinc and nickel by N~2~O~5~ led, respectively, to turquoiseβcoloured single crystals of (NO)Cu(NO~3~)~3~ [monoclinic, __P__2~1~/__m__, __Z__ = 2, __a__ = 465.90(5), __b__ = 1111.7(1), __c__ = 700.7(1) pm, __Ξ²__ = 100.70(2)Β°, __wR__~2~ = 0.0566], lightβyellow sin
Metal Oxidation with N 2 O 5 : The Nitrosylium Nitrates (NO)Cu(NO 3 ) 3 , (NO)2[Zn(NO3)4] and (NO)6[Ni4(NO3)12](NO3)2β’(HNO3). -N2O5 is prepared by reaction of fuming HNO3 with P4O10 and directly condensed on the metal powders. The crystal structures of the resulting title compounds are determined by