New Volatile Nitronium Nitratometalates: NO2[Fe(NO3)4] and NO2[Zr(NO3)5] — Synthesis and Crystal Structure
✍ Scribed by G. Tikhomirov; I. Morozov; K. Znamenkov; E. Kemnitz; S. Troyanov
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- German
- Weight
- 371 KB
- Volume
- 628
- Category
- Article
- ISSN
- 0372-7874
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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100±140 °C during 3±12 h. X-ray single crystal structures for isotypic I and II reveal the presence of
## Crystalline cesium nitratometalates(II), Cs 2 [M(NO 3 ) 4 ] (M = Mn (I), Co (II), Ni (III), and Zn (IV)) were synthesized from M(NO 3 ) 2 ´n H 2 O and CsNO 3 by heating at 80±120 °C over 10±12 h. According to X-ray crystal structure analysis, the compounds are built from Cs + cations and [M(NO