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New Volatile Nitronium Nitratometalates: NO2[Fe(NO3)4] and NO2[Zr(NO3)5] — Synthesis and Crystal Structure

✍ Scribed by G. Tikhomirov; I. Morozov; K. Znamenkov; E. Kemnitz; S. Troyanov


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
371 KB
Volume
628
Category
Article
ISSN
0372-7874

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## Crystalline cesium nitratometalates(II), Cs 2 [M(NO 3 ) 4 ] (M = Mn (I), Co (II), Ni (III), and Zn (IV)) were synthesized from M(NO 3 ) 2 ´n H 2 O and CsNO 3 by heating at 80±120 °C over 10±12 h. According to X-ray crystal structure analysis, the compounds are built from Cs + cations and [M(NO