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ChemInform Abstract: New Volatile Nitronium Nitratometalates: NO2[Fe(NO3)4] and NO2[Zr(NO3)5] — Synthesis and Crystal Structure.

✍ Scribed by G. Tikhomirov; I. Morozov; K. Znamenkov; E. Kemnitz; S. Troyanov

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200229010

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Metal Oxidation with N 2 O 5 : The Nitrosylium Nitrates (NO)Cu(NO 3 ) 3 , (NO)2[Zn(NO3)4] and (NO)6[Ni4(NO3)12](NO3)2•(HNO3). -N2O5 is prepared by reaction of fuming HNO3 with P4O10 and directly condensed on the metal powders. The crystal structures of the resulting title compounds are determined by