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Synthesis and Crystal Structure of Two One-dimensional Chain Copper Complexes [Cu(TTA)2(4,4′-azpy)] and [Cu(TTA)2(3,3′-azpy)]

✍ Scribed by Li Bao-Long; Lang Jian-Ping; Chen Jing; Zhang Yong; Zheng Li-Min


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
347 KB
Volume
21
Category
Article
ISSN
0256-7660

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Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) ä, V 76