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Synthesis and Crystal Structure of the Complexes [(n-Bu)4N]2 [{(THF)Cl4ReN}2PdCl2], [Ph4P]2 [(THF)Cl4ReN-PdCl(μ-Cl)]2 and [(η-Bu)4N]2[Pd3Cl8].

✍ Scribed by Simon Schwarz; Joachim Straehle; Ulrike Weisser


Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis and Crystal Structures of the
✍ D. V. Griffiths; S. J. Parrott; M. Togrou; J. R. Dilworth; Yifan Zheng; S. Ritte 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 141 KB 👁 2 views

Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure