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Synthese und Struktur der Komplexe [(n-Bu)4N]2[{(THF)Cl4Re≡N}2PdCl2], [Ph4P]2[(THF)Cl4Re≡N-PdCl(μ-Cl)]2 und [(n-Bu)4N]2[Pd3Cl8]

✍ Scribed by Simon Schwarz; Joachim Strähle; Ulrike Weisser


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
106 KB
Volume
628
Category
Article
ISSN
0372-7874

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📜 SIMILAR VOLUMES


Synthese und Struktur der Nitrido-Komple
✍ Simon Schwarz; Joachim Strähle 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 105 KB

Inhaltsübersicht. Der heteronukleare Dreikernkomplex [(n-Bu) 4 N] 2 [{(THF)Cl 4 ReϵN} 2 PtCl 2 ] (1a) entsteht bei der Reaktion von [(n-Bu) 4 N][ReNCl 4 ] mit [PtCl 2 (C 6 H 5 CN) 2 ] in THF/CH 2 Cl 2 in Form roter, solvathaltiger Kristalle. Er kristallisiert als 1a • 2 CH 2 Cl 2 in der tetragonalen

(Bu4N)[Re{NB(C6F5)3}Cl4(OH2)] – Struktur
✍ U. Abram; F. J. Kohl; K. Öfele; W. A. Herrmann; A. Voigt; R. Kirmse 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 74 KB

The title compound represents the first structurally characterized rhenium(VI) complex with a bridging nitrido ligand. It has been prepared by the reaction of (Bu 4 N)[ReNCl 4 ] with B(C 6 F 5 ) 3 in CH 2 Cl 2 . An almost linear (170.5(3)°) nitrido bridge with a Re≡N bond length of 1.672(4) A Ê is f