The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2 H)-thione-5-one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 (1). 1 was characterized by IR and 13 C NMR spectroscopy and by an X-ray structure analysis [space group C2/c, Z = 4, lattice dimensions at ±80 °C: a =
Synthesis and crystal structure of pentabenzylcyclopentadienylindium(I)
✍ Scribed by Herbert Schumann; Christoph Janiak; Frank Görlitz; Jörg Loebel; Andreas Dietrich
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 593 KB
- Volume
- 363
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The reaction of copper(I) chloride with acetonethiosemicarbazone (tscac) in a copper to tscac molar ratio of 1:2 forms the cationic complex [Cu(tscac)~2~]Cl (1). When the ratio of the copper to tscac was reduced to 1:1, a dimeric complex [Cu~2~Cl~2~(tscac)~2~]~2~ (2) was obtained. In co