## Abstract Eight Schiff bases of 3‐amino‐1__H__‐1,2,4‐triazole have been synthesized by glacial acetic acid catalyzed condensation of 3‐amino‐1__H__‐1,2,4‐triazole with substituted benzaldehyde and structurally confirmed by IR, ^1^H NMR and elemental analysis. The preliminary bioassay showed that
Synthesis and crystal structure of novel schiff bases derived from 3-(2-ethoxyphenyl)-4-amino-5-mercapto-4H-1,2,4-triazole
✍ Scribed by San-nu Zhou; Li-xue Zhang; An-jiang Zhang; Ji-shun Sheng; Hai-le Zhang
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 394 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
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A series of novel 4‐(arylmethylidene)amino‐5‐(2‐ethoxyphenyl)‐3‐mercapto‐4__H__‐1,2,4‐triazoles (2a‐f) were easily synthesized in high yields by means of the reactions of 3‐(2‐ethoxyphenyl)‐4‐amino‐5‐mercapto‐4__H__‐1,2,4‐triazole (1) with various aromatic aldehydes. The compound, 4‐(4‐methylbenzylidene)‐amino‐5‐(2‐ethoxyphenyl)‐3‐mercapto‐4__H__‐1,2,4‐triazole was investigated with X‐ray crystallography.
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Four triorganotin complexes of the types [(Ph 3 Sn)(C 15 H 10 FN 4 S)] (3), [(CH 3 ) 3 Sn (C 15 H 10 FN 4 S)] n (4), [(Ph 3 Sn)(C 13 H 9 FN 4 S 2 )] (5), and [(CH 3 ) 3 Sn(C 13 H 9 FN 4 S 2 )] n ( 6) have been obtained by Schiff base compound 1 (derived from 4fluorobenzaldehyde) and compound 2 (deri
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