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Syntheses and crystal structures of triorganotin(IV) complexes of schiff base derived from 4-amino-5-phenyl-4H-1,2,4-trizole-3-thiol

✍ Scribed by Chunlin Ma; Qingfeng Wang; Rufen Zhang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
311 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Four triorganotin complexes of the types [(Ph 3 Sn)(C 15 H 10 FN 4 S)] (3), [(CH 3 ) 3 Sn (C 15 H 10 FN 4 S)] n (4), [(Ph 3 Sn)(C 13 H 9 FN 4 S 2 )] (5), and [(CH 3 ) 3 Sn(C 13 H 9 FN 4 S 2 )] n ( 6) have been obtained by Schiff base compound 1 (derived from 4fluorobenzaldehyde) and compound 2 (derived from thiophene-2-carboxadehyde) with triorganotin chloride in the presence of sodium ethoxide. All the complexes were characterized by elemental analysis, IR, and NMR spectroscopies, and X-ray diffraction analyses, which revealed that complexes 3 and 5 are mononuclear structures, complex 4 and 6 are onedimensional zigzag infinite chains via N → Sn and S → Sn bonding interactions.

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