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Synthesis and Crystal Structure of New Early-Lanthanide Organometallic Clusters

✍ Scribed by Eyal Barnea; Claudia Averbuj; Moshe Kapon; Mark Botoshansky; Moris S. Eisen

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 237 KB
Volume: 2007
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200601167

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## Abstract A new series of oxovanadium(IV)–lanthanide(III) heteronuclear complexes [Yb(H~2~O)~8~]~2~[(VO)~2~(TTHA)]~3~⋅21 H~2~O (1), {[Ho(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}⋅ 8.5 H~2~O (2), {[Gd(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}⋅8.5 H~2~O (3), {[Eu(H~2~O)~7~][(VO)~2~(TTHA)]~1.5