Synthesis, crystal structure and properties of a new lanthanide-transition metal carbonyl cluster
โ Scribed by Jiehui Ye; Haiquan Su; Fenghua Bai; Yong Du; Yulong Zhang
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 131 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.1476
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Needle-shaped, moisture sensitive, yellow crystals of Na 3 TaS 4 were obtained by the reaction of Na 2 S 3 , Ta, and S at 450 ยฐC. The structure was determined by single crystal X-ray diffraction and refined to R1 and wR2 values of 0.0172 and 0.0381, respectively. Na 3 TaS 4 crystallizes with 32 form