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Synthesis and Crystal Structure of [K([2.2]crypt)]2[HgGe9](dmf).

✍ Scribed by M. Bele Boeddinghaus; Stephan D. Hoffmann; Thomas F. Faessler


Publisher
John Wiley and Sons
Year
2007
Weight
16 KB
Volume
38
Category
Article
ISSN
0931-7597

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The [Sn5]2– Cluster Compound [K-(2,2,2-c
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Dark red crystals of [K-(2,2,2)-crypt)] 2 Sn 5 precipitate after the reaction of (2,2,2)-crypt with a solution of K 1.33 Sn in liquid ammonia at room temperature. The compound is sensitive to oxidation and hydrolysis. The sequence of Raman bands (104, 120, 133 and 180 cm Β±1 ) is characteristic for t