Extraction of Ternary Alloys: Synthesis and Crystal Structure of [K([2.2.2]crypt)]Cs7[Sn9]2(en)3
✍ Scribed by Ralf Hauptmann; Rudolf Hoffmann; Thomas F. Fässler
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 212 KB
- Volume
- 627
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
By solid state reaction two new layered perovskites have been synthesized related to the Ruddlesden-Popper family, K
Synthetic Cs(VO 2 ) 3 (TeO 3 ) 2 is built up from infinite sheets of distorted octahedral V V O 6 groups, sharing vertices. These octahedral layers are ªcappedº by Te atoms (as parts of pyramidal [Te IV O 3 ] 2± groups) on both faces of each V/O sheet, with inter-layer, 12-coordinate, Cs + cations p
Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) ä, V 76
The possibility to synthesize and isolate different types of bismuth polyanions by dissolving various intermetallic precursors (binary samples from A-Bi or ternary samples from A-A'-Bi systems, A and A' ϭ K, Rb, Cs) in ethylenediamine or dimethylformamide in the presence of sequestering agents (2,2,