Synthesis and crystal structure of 1,6-Bis-(N,Ndiethylaminothiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexane are reported as well as those of its dimeric Ag I complex (as monotoluene adduct of the diperchlorate) and its tetrameric l-tetrabromo Ag I complex.
Synthesis and Crystal Structure of {[HNEt3]2n[Ag8Ag4/2(SC6H4tBu-4)12]n·nC2H5OH} and Its Reaction Product with CS2
✍ Scribed by Kaluo Tang; Xiangjin Xie; Liang Zhao; Yaohua Zhang; Xianglin Jin
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 252 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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4, 6) 1, (1) reacts with a small amount of CS2 to give red crystals [ c u 6 ( s ~s c ~2 P r ' 3 - 2,4,6)2] .2CHCl3 . 4CH30H (2), and CS2 is inserted into two-thirds of the Cu-S bonds of complex (1). The unusual structure of complex (2) consists of six copper atoms linked through arenethiolate (RS-
## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3