Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi
Synthesis and Crystal Structure of 1,6-Bis(N,N-diethylthiocarbamoylimino)1,6-diphenyl-2.5-dithiahexane, its Dimeric AgI Complex [Ag2(C26H34N4S4)2](ClO4)2 · C7H8, and its Tetrameric μ-Tetrabromo AgI Complex [Ag4(C26H34N4S4)2Br4]
✍ Scribed by S. Bender; E. Hoyer; G. Zahn
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- German
- Weight
- 145 KB
- Volume
- 625
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
Synthesis and crystal structure of 1,6-Bis-(N,Ndiethylaminothiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexane are reported as well as those of its dimeric Ag I complex (as monotoluene adduct of the diperchlorate) and its tetrameric l-tetrabromo Ag I complex.
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