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Insertion of CS2 into CuS bonds (II). Preparation and crystal structure of insertion product with CS2 [Cu6(S2CSC6H2Pri3-2,4,6)4(SC6H2Pri3-2,4,6)2] · 2CHCl3 · 4CH3OH

✍ Scribed by Kaluo Tang; Dedong Wu; Xianglin Jin; Youqi Tang

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
363 KB
Volume
3
Category
Article
ISSN
1042-7163

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✦ Synopsis

4,

1, (1) reacts with a small amount of CS2 to give red crystals [ c u 6 ( s ~s c ~2 P r ' 3 - 2,4,6)2] .2CHCl3 . 4CH30H (2), and CS2 is inserted into two-thirds of the Cu-S bonds of complex (1). The unusual structure of complex (2) consists of six copper atoms linked through arenethiolate (RS-) and aryl trithiocarbonate (RSCS2-) ligands, exhibiting a number of interesting features.

2,4,6),(SC6H2P+3-

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